Hydrolysis of Activated Amides Around the Temperature of Maximum Density of Water – Isochoric Conditions1
ثبت نشده
چکیده
منابع مشابه
Kinetics of hydrolysis of 1-benzoyl-1,2,4-triazole in aqueous solution as a function of temperature near the temperature of maximum density, and the isochoric controversy.
At temperatures above and below the temperature of maximum density, TMD, for water at ambient pressure, pairs of temperatures exist at which the molar volumes of water are equal. First-order rate constants for the pH-independent hydrolysis of 1-benzoyl-1,2,4-triazole in aqueous solution at pairs of such isochoric temperatures show no unique features. Taken together with previously published kin...
متن کاملTheoretical study of the effect of internal strain on the bond length and rate of hydrolysis in cyclic amides
The internal strain in cyclic amides are explained as a factor of resonance that are effected on the bond length C-N and are a major factor of rates of hydrolysis. The cyclic amides in this study are optimized by Gaussian program and the bond length of C-N in the rings are studied by HF/6-31G*.
متن کاملInternal strain on the bond length and rate of hydrolysis in cyclic amides
The internal strain in cyclic amides are explained as a factor of resonance that are effected on the bond length C-N and are a major factor of rates of hydrolysis. The cyclic amides in this study are optimized by Gaussian program and the bond length of C-N in the rings are studied by HF/6-31G*.
متن کاملTheoretical study of the effect of internal strain on the bond length and rate of hydrolysis in cyclic amides
The internal strain in cyclic amides are explained as a factor of resonance that are effected on the bond length C-N and are a major factor of rates of hydrolysis. The cyclic amides in this study are optimized by Gaussian program and the bond length of C-N in the rings are studied by HF/6-31G*.
متن کاملEffect of Metal Salt Coagulants on Treatment of Activated Sludge Effluent in Sulfite Mill Pulp and Paper Plant
Pulp and paper effluents are considered as serious environmental hazards and their treatment, because of multiplicity of impurities and complexity of their chemical structures, is one of the most difficult and inconvenient industrial processes. As the most pulp and paper mill work on kraft process, there are few studies in literature on the treatment of neural sulfite semi chemical (NSSC) p...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2017